Biotite

Biotite--K(Mg,Fe)3AlSi3O10(OH)2--is a dark, iron-rich mica that has a monoclinic crystal system. The octahedral layer is entirely occupied by Mg2+ and Fe2+ and the mineral is therefore trioctahedral, since all octahedra are occupied. The source of the lattice charge is the presence of Al3+ in place of Si4+ in 1/4 of the tetrahedral sites. The interlayer potassium is neatly nested among 12 oxygens and 2 hydroxyl groups, half from each layer.

Highlighting Features

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Magnesium (Mg) atoms
Aluminum (Al) atoms
Silicon (Si) atoms
Oxygen (O) atoms
Iron (Fe) atoms
Potassium (K) atoms
Potassium (K) and nearest neighbors
Single potassium (K) and nearest neighbors (12 O and 2 OH-)
All atoms

Distribution

Biotite occurs worldwide in granites, gabbros, schists, and gneisses.

Crystallographic Data

Reference

Brigatti, M. F., and P. Davoli. 1990. Crystal-structure refinement of 1M plutonic biotites sample M62 from a rock transitional between granitic and monzonitic in the Valle del Cervo pluton. American Mineralogist. 75:305-313


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Original release: 1 Oct 1998;